In 2019, EFSA published a statement on the review of the risk related to the exposure to food additive titanium dioxide (E171) performed by the French Agency for Food, Environment and Occupational Health Safety (ANSES). In its statement, EFSA highlighted that the ANSES opinion reiterated the uncertainties and data gaps previously identified by EFSA and did not present findings that invalidated the Authority’s previous conclusions on the safety of titanium dioxide.
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In industrial settings, people can be exposed to titanium dioxide through inhalation. Inhalation exposure to titanium dioxide is exceedingly rare for most people.
Polyvinyl butyral (PVB) is dissolved into 12 ~ 14% solution with ethanol and made into film. It is used for printing paper film of ceramic (or enamel) products. The fired ceramic (or enamel) patterns have bright color and smooth texture. The flower paper is characterized by convenient use, low cost, smaller than the original glue, greatly reducing the decal process and high color burning rate. At present, most porcelain factories in China have formed relatively formal production lines for standardized production. Therefore, the demand for PVB in the ceramic (or enamel) flower paper industry is increasing.
Application field of polyvinyl butyral -- electronic adhesive
Polyvinyl butyral contains hydroxyl, vinyl acetate and butyraldehyde, which has high bonding properties. Phenolic Resin was added into PVB ethanol solution to make adhesive, which can be used for a long time at 120 ℃. The product has strong adhesion to metal, wood, leather, glass, fiber and ceramics; FRP can be manufactured to replace non-ferrous metals such as steel, aluminum and copper; The adhesive made by adding this product and curing agent into epoxy resin is often used for bonding and assembly of electronic instrument components, bonding between metal and porous materials, emergency repair, etc. it can also be used in the field of electronic ceramics. In the development of ceramic integrated electronic circuits, this product with medium viscosity and low hydroxyl is used as ceramic powder adhesive to increase the primary strength of ceramics.
Application field of polyvinyl butyral -- copper foil adhesive
Polyvinyl butyral (PVB) and phenolic resin cooperate to produce copper foil adhesive, which is used in the production of copper clad laminate. It has good peel strength and tin welding temperature resistance, and is widely used in various fields.
Application field of polyvinyl butyral - self adhesive enamelled wire paint
Polyvinyl butyral is the main raw material of self-adhesive enamelled wire paint. After the enameled wire is wound and formed in the electrodes of motors, electrical appliances and instruments, as long as it is heated for several minutes at a certain temperature or treated with appropriate solvent, the coils can be bonded together by themselves without impregnation and drying.
It offers several advantages in various applications. Its excellent opacity and brightness make it a popular choice in the production of paints, coatings, and printing inks, providing a cost-effective alternative to titanium dioxide. Lithopone's chemical stability enhances its durability in outdoor environments, making it suitable for outdoor coatings. Additionally, its low reactivity and compatibility with other pigments contribute to its versatility. Beyond coatings, lithopone finds utility in plastics, rubber, and paper industries. Overall, its multifaceted advantages and broad applications underscore this compound's significance in diverse industrial sectors.
Duan et al. administered 125 mg/kg BW or 250 mg/kg BW of anatase TiO2 (5 nm) intragastrically to mice continuously for 30 days. The exposed mice lost body weight, whereas the relative liver, kidney, spleen and thymus weights increased. Particles seriously affected the haemostasis of the blood and the immune system. The decrease in the immune response could be the result of damage to the spleen, which is the largest immune organ in animals and plays an important role in the immune response. Powel et al. demonstrated that TiO2 NPs may trigger immune reactions of the intestine after oral intake. They showed that TiO2 NPs conjugated with bacterial lipopolysaccharide, but not TiO2 NPs or lipopolysaccharide alone, trigger the immune response in human peripheral blood mononuclear cells and in isolated intestinal tissue. This indicates that TiO2 NPs may be important mediators in overcoming normal gut-cell hyporesponsiveness to endogenous luminal molecules, which may be particularly relevant to patients with inflammatory bowel disease, which is characterized by an abnormal intestinal permeability.
In Europe, the downstream paints and coatings sector presented weak demand in front of the titanium dioxide manufacturers, and thus, the titanium dioxide price trend experienced a gradual decline in its trajectory. Additionally, the pressure of inflation and increasing bank interest rates lowered the spending appetite of consumers which had an adverse effect on the titanium dioxide price trends. Further, the export and import of titanium dioxide were also caught under the negative influence of the poor economic conditions of the market.
The FDA is reviewing the safety of titanium dioxide in response to an April petition from EWG and other environmental and public health groups. This is the FDA’s first comprehensive review of titanium dioxide since 1973.
Overall, Chinese anatase titanium dioxide stands out as a versatile and valuable material with a wide range of applications in various industries. Its unique properties make it a popular choice for use in pigments, sunscreen, environmental remediation, and energy conversion technologies. As research into this material continues to expand, we can expect to see even more innovative uses and advancements in the field of materials science.
The North American region suffered from the excess influx of material in the market, especially from the Asian countries, in the first half of the third quarter. The quarter, however, showed signs of significant improvement with a rise in the number of offtakes. Further, the lack of labor in the US challenged the rates of production of titanium dioxide and resulted in the depletion in the level of existing inventories, pushing the titanium dioxide price graph in an upward direction.